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Annelated Cyclobutanes by Fe‐Catalyzed Cycloisomerization of Enyne Acetates |
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| Authors: | M. Sc. Frederik Kramm M. Sc. Johannes Teske M. Sc. Franziska Ullwer Wolfgang Frey Prof. Dr. Bernd Plietker |
| Affiliation: | Institut für Organische Chemie, Universit?t Stuttgart, Stuttgart, Germany |
| Abstract: | Cationic Fe complexes of the general type [(Ph3P)2Fe(CO)(NO)]X (X=BF4, BArF4) catalyze the redox‐neutral cycloisomerization of 1,6‐ and 1,7‐enyneacetates to afford bicyclic cyclobutanes under mild conditions in good yields and diastereoselectivities. |
| Keywords: | catalysis cyclobutane enynes iron isomerization |