| Hydrodesulfurization of Thiophene on Ni,Mo-supported MCM-41 Catalysts |
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| 作者姓名： | CUI Jun YUE Ying hong SUN Yu DONG Wei yang and GAO Zi ** |
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| 作者单位： | Department of Chemistry，Fudan University，Shanghai，200433 |
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| 摘 要： | ＩｎｔｒｏｄｕｃｔｉｏｎＴｈｅｒｅｃｅｎｔｄｉｓｃｏｖｅｒｙｏｆｎｏｖｅｌｅｘｔｒａｌａｒｇｅｍｅｓｏｐｏｒｏｕｓＭＣＭ－４１ｍｏｌｅｃｕｌａｒｓｉｅｖｅｓ［１，２］ｆｉｌｓｔｈｅｇａｐｂｅｔｗｅｅｎｍｉｃｒｏｐｏｒｏｕｓａｎｄｍａｃｒｏｐｏｒｏｕｓ...
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Hydrodesulfurization of Thiophene on Ni, Mo supported MCM 41 Catalysts * |
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| CUI Jun,YUE Ying hong,SUN Yu,DONG Wei yang and GAO Zi **.Hydrodesulfurization of Thiophene on Ni,Mo-supported MCM-41 Catalysts[J].Chemical Research in Chinese University,1998(3). |
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| Authors: | CUI Jun YUE Ying hong SUN Yu DONG Wei yang and GAO Zi |
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| Institution: | CUI Jun,YUE Ying hong,SUN Yu,DONG Wei yang and GAO Zi ** |
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| Abstract: | MoO 3 and NiO supported MCM 41 and AlMCM 41 catalysts were prepared. The XRD and N 2 adsorption/desorption results show that MoO 3 was more readily dispersed on the supports than NiO. The activities of the catalysts for thiophene hydrodesulfurization are strongly affected by the block of the unidimensional mesoporous channels with oxide crystallites and/or extra framework impurities. Mo supported MCM 41 catalysts are more active for hydrodesulfurization than Ni and Ni, Mo supported MCM 41 catalysts. |
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| Keywords: | MCM 41 Dispersion of MoO 3 and NiO Thiophene hydrodesulfurization |
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