Assembly of polymeric silver(I) complexes of isomeric phenylenediethynides with the supramolecular synthons Agn subset C2-R-C2 superset Agn (R = p-, m-, o-C6H4; n = 4, 5) |
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| Authors: | Zhao Liang Mak Thomas C W |
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| Institution: | Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, P. R. China. |
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| Abstract: | New Agn subset C2-R-C2 supersetAgn (R = p-, m-, o-C6H4; n = 4, 5) supramolecular synthons have been explored in the coordination network assembly of silver(I) complexes of the isomeric phenylenediethynides. An unprecedented mu5-eta1-coordination mode for the ethynide moiety and a mixed mu4,mu5-coordination mode for the o-phenylenediethynide group are observed, providing a rationale for the abundant occurrence of C2@Agn (n
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