One-dimensional silver(I) chain of lacunary alpha-Keggin anions |
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| Authors: | Nogueira Helena I S Paz Filipe A Almeida Teixeira Paula A F Klinowski Jacek |
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| Institution: | Department of Chemistry, CICECO, University of Aveiro, 3810-193, Aveiro, Portugal. helena@dq.ua.pt |
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| Abstract: | A novel chain-like silver polyoxotungstophosphate is formed when Ag(I) metal centres, exhibiting an unusual eight-coordination fashion, bridge a monolacunary PW11O39]7- anion to four bridging mu2-oxygen atoms of a neighbouring lacunary alpha-Keggin anion. |
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