Hydrazinium(1+) hexafluorogermanate(IV) and hydrazinium(2+) hexafluorogermanate(IV) difluoride |
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Authors: | D Gantar L Golic̆ I Leban A Rahten |
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Institution: | ‘Joz?ef Stefan’ Institute and Chemistry Department, ‘Edvard Kardelj’ University, Ljubljana, Yugoslavia |
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Abstract: | (N2H5)2GeF6 and (N2H6)2(GeF6)F2 have been prepared by reactions of N2H4·H2O and N2H6F2 with fluorogermanic acid. The solids have been characterized by chemical analysis and vibrational spectra. X-ray diffraction study has shown that crystals of (N2H5)2GeF6 are monoclinic, space group P 21/n, with unit-cell dimensions a = 6.015 (2), b = 5.249 (1), c = 11.181 (2) Å, β = 100.15 (2)o, and Z = 2. There are N2H5+ cations and GeF62? anions in the crystals interconnected by hydrogen bonds of the type NH····F and NH····N. |
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