Free radical chemistry. Part 5. [1] A new approach to the synthesis of perfluorinated ethers |
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| Authors: | Richard D. Chambers Brian Grievson Frederick G. Drakesmith Richard L. Powell |
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| Affiliation: | Department of Chemistry, University Science Laboratories, South Road, Durham, DH1 3LE U.K.;Electricity Council Research Laboratories, Capenhurst, Chester CH1 6ES U.K.;I.C.I. p.l.c., Mond Division, Runcorn, Cheshire WA7 4QD U.K. |
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| Abstract: | Fluorinations of the free-radical adducts of fluorinated alkenes, to ethers, over cobalt trifluoride are described and perfluorinated ethers are obtained at temperatures in excess of 400°C. The effect of structure on the formation of perfluoroethers is outlined. |
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