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| Synthesis and Crystal Structure of a Novel Mercapto-organotin Complex: [Et_3NH] [Ph_2SnCl(μ~2-SCH_2COO~-)] | |
| 作者姓名： | Xue Qing SONG Qing Lan XIE Xiao Niu FANG |
| 作者单位： | Institute of Elemento-organic Chemistry，Nankai University，300071，Tianjin Department of Chemistry，Ji'an Teachers' college，343009，JI'an，Jiangxi |
| 摘 要： | Diorganotinmercaptoacetates,generallyusedforPVCstabilizer',havebeensynthesizedbythereactionofdiorganotindichloridesandmercaptoaceticacidinthepresenceofanorganicbase,butthereactionsbetweentriorganotinchloridesandmercaptoaceticacidhavebeenlittlestudied.Inthispaper,wereportanewdephenylationreactionandcrystalstructureofanunexpectedcomplexEt3NH]Ph,SnCI(rf-SCHZCOO-)].WehaveexpectedtosynthesizePh3SnSCHZCOOSnph3bythereactionofPh3SnCIandHSCHZCOOHin2:lmolarratiointhepresenceoforganicba… |
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