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Composites Based on Polystyrene Microspheres with Nano-Scaled Titanium Dioxide
Authors:Nataliya S. Serkhacheva  Asiya A. Gainanova  Galina M. Kuz’micheva  Vadim V. Podbelskiy  Nataliya V. Sadovskaya  Andrey M. Zybinskiy
Affiliation:1. Department of Macromolecular Compounds, Lomonosov State University of Fine Chemical Technologies, Moscow, Russia;2. Department of Materials Science and Technology of Functional Materials and Structures, Lomonosov State University of Fine Chemical Technologies, Moscow, Russia;3. Department of Software Engineering, National Research University “Higher School of Economics,” Moscow, Russia;4. Department of Materials Science, Karpov Institute of Physical Chemistry, Moscow, Russia;5. Analytics Department, N. M. Fedorovsky All-Russian Research Institute of Mineral Raw Materials, Moscow, Russia
Abstract:This study produced for the first time composites based on polystyrene microspheres with nano-sized titania synthesized by sulfate and sol-gel methods, as well as commercial Hombifine N, Hombikat UV100, and Degussa P25. The starting samples and the composites were characterized by X-ray diffraction, scanning electron microscopy, nitrogen adsorption capacity, and IR spectroscopy. The highest content of nano-titanium dioxide both in the bulk and on the surface of microspheres was obtained with the use of Hombikat UV100. This sample has the largest specific surface area and a high content of reactive OH groups. The adsorption properties of composites were investigated.
Keywords:Heterophase polymerization  Nano-scaled titanium dioxide  Polymer composites  Polystyrene microspheres  X-ray amorphous titanium dioxide
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