Hydrogenation of cinnamaldehyde over platinum catalysts: influence of addition of metal chlorides |
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| Institution: | 1. Department of Biochemistry, University of Texas Southwestern Medical Center, Dallas, TX 75390, United States;2. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Facultad de Ciencias Exactas y Naturales, Universidad de Belgrano, Villanueva 1324, Buenos Aires C1426BMJ, Argentina;3. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), CONICET, UNLP, Diag. 113 y 64, C.C. 16, Sucursal 4, 1900 La Plata, Argentina;1. Instituto de Química, UNAM, Mexico City, Mexico;2. Unidad de Investigación en Reproducción Humana, Instituto Nacional de Perinatología-Facultad de Química, UNAM, Mexico City, Mexico;3. Lab. Fitofarmacología, Depto. de Farmacología, Facultad de Medicina, UNAM; México City, Mexico;4. Laboratory of Cell and Developmental Signaling, Center for Cancer Research, National Cancer Institute, Frederick, U.S.A. |
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| Abstract: | The effect of addition of metal chlorides to platinum-supported catalysts has been studied in the hydrogenation of cinnamaldehyde in the liquid phase. FeCl3, SnCl4 and GeCl4 were found to be the most effective promoters for the selective synthesis of cinnamyl alcohol. The rate of reaction increased by addition of small amounts of metal chlorides and then decreased at higher contents. Selectivity to cinnamyl alcohol was slightly dependent on the concentration of the additives and on the level of conversion.A reaction mechanism for the hydrogenation of cinnamaldehyde over promoted platinum is suggested. |
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