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In Situ Immobilization of Palladium Nanodots in C−C Bonded 2D Conjugated Polymers through Suzuki Polymerization at the Liquid–Liquid Interface
Authors:Dongyang Wang  Prof Ming Li
Institution:Hubei Collaborative Innovation Center for Advanced Organic Chemical, Materials, Ministry-of-Education Key Laboratory for the Synthesis, and Application of Organic Functional Molecules, Hubei Key Laboratory of Polymer Materials, College of Chemistry and Chemical Engineering, Hubei University, Wuhan, 430062 P. R. China
Abstract:Traditional methods for immobilization of noble metal nanodots in 2D materials (2DMs) need multiple steps and unfriendly reaction conditions. Herein, a one-step method was developed by immobilizing in situ palladium nanodots during the preparation of the 2D conjugated polymer (2DCP) through Suzuki polymerization on interface under mild conditions. Through this method, three 2D conjugated nanosheets carrying palladium nanodots were synthesized.
Keywords:2D conjugated polymers  immobilization  interface  palladium nanodots  Suzuki polymerization
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