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Advances in Artificial Layers for Stable Lithium Metal Anodes
Authors:Dr Liya Qi  Zhengwei Wu  Binglu Zhao  Bojun Liu  Wenyun Wang  Dr Hao Pei  Yuqing Dong  Dr Shijun Zhang  Dr Zhengjin Yang  Dr Liangliang Qu  Dr Weixia Zhang
Institution:1. John?A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, MA, 02138 USA

SINOPEC, Beijing Research Institute of Chemical Industry, Beijing, 100013 China

These authors contributed equally to this work.;2. John?A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, MA, 02138 USA

Department of Biomedical Engineering and Biotechnology, University of Massachusetts Lowell, Lowell, MA, 01854 USA

These authors contributed equally to this work.;3. College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871 China

These authors contributed equally to this work.;4. John?A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, MA, 02138 USA

School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, Anhui, 230026 China;5. John?A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, MA, 02138 USA

Chemistry Department, Mount Holyoke College, South Hadley, MA, 01075 USA;6. John?A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, MA, 02138 USA;7. John?A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, MA, 02138 USA

Bioinspired Engineering and Biomechanics, Xi'an Jiaotong University, Xi'an, Shaanxi, 710049 China;8. SINOPEC, Beijing Research Institute of Chemical Industry, Beijing, 100013 China;9. CAS Key Laboratory of Soft Matter Chemistry, Collaborative Innovation Centre of Chemistry for Energy Materials, School of Chemistry and Material Science, University of Science and Technology of China, Hefei, 230026 China

Abstract:Lithium (Li) metal is considered as the most promising anode material for rechargeable high-energy batteries. Nevertheless, the practical implement of Li anodes is significantly hindered by the growth of Li dendrites, which can cause severe safety issues. To inhibit the formation of Li dendrites, coating an artificial layer on the Li metal anode has been shown to be a facile and effective approach. This review mainly focuses on recent advances in artificial layers for stable Li metal anodes. It summarizes the progress in this area and discusses the different types of artificial layers according to their mechanisms for Li dendrite inhibition, including regulation of uniform deposition of Li metal and suppression of Li dendrite growth. By doing this, it is hoped that this contribution will provide instructional guidance for the future design of new artificial layers.
Keywords:artificial layers  lithium dendrites  lithium metal batteries  mechanical suppressing  uniform deposition
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