Optically Triggered Control of the Charge Carrier Density in Chemically Functionalized Graphene Field Effect Transistors |
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Authors: | Zian Tang Dr Antony George Dr Andreas Winter David Kaiser Christof Neumann Dr Thomas Weimann Prof?Dr Andrey Turchanin |
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Institution: | 1. Institute of Physical Chemistry, Friedrich Schiller University Jena, Lessingstraße 10, 07743 Jena, Germany;2. Physikalisch-Technische Bundesanstalt (PTB), Bundesallee 100, 38116 Braunschweig, Germany |
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Abstract: | Field effect transistors (FETs) based on 2D materials are of great interest for applications in ultrathin electronic and sensing devices. Here we demonstrate the possibility to add optical switchability to graphene FETs (GFET) by functionalizing the graphene channel with optically switchable azobenzene molecules. The azobenzene molecules were incorporated to the GFET channel by building a van der Waals heterostructure with a carbon nanomembrane (CNM), which is used as a molecular interposer to attach the azobenzene molecules. Under exposure with 365 nm and 455 nm light, azobenzene molecules transition between cis and trans molecular conformations, respectively, resulting in a switching of the molecular dipole moment. Thus, the effective electric field acting on the GFET channel is tuned by optical stimulation and the carrier density is modulated. |
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Keywords: | 2D materials chemical functionalization field effect transistors graphene photoresponsive devices |
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