Environmentally Benign,Intrinsically Coordinated,Lithium-Based Solid Electrolyte with a Modified Purine as Supporting Ligand

Bioinspired materials have become increasingly competitive for electronic applications in recent years owing to the environment-friendly alternatives they offer. The notion of biocompatible solid organic electrolytes addresses the issues concerning potential leakage of corrosive liquids, volatility and flammability of electrolyte solvents. This study presents a new intrinsically coordinated Li^I adenine complex that exhibits electrical conductivity as a solid electrolyte capable of self-sustained supply of Li^I ions. It exhibits conductivity through moisture-assisted Li^I ion motion up to 373 K, and possibly by an ion-hopping mechanism beyond 373 K. This purine-derived solid electrolyte shows enhanced conductivity and transference number demonstrating the potential of purine-based ligands and their coordination complexes in interesting materials applications.