Palladium-Catalyzed Annulation of Acyl Fluorides with Norbornene via Decarbonylation and CO Reinsertion |
| |
| Authors: | Yuka Sakurai Dr. Yohei Ogiwara Prof. Dr. Norio Sakai |
| |
| Affiliation: | Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science, Noda, Chiba, 278-8510 Japan |
| |
| Abstract: | A palladium-catalyzed annulation of acyl fluorides with norbornene is described. This study reports the first example of an annulation of acyl fluorides in the presence of a transition-metal catalyst. Polycyclic ketones are obtained from the cleavage of the C−F and C−H bonds of the acyl fluoride and the rearrangement of the carbonyl moiety by decarbonylation and CO reinsertion. |
| |
| Keywords: | acyl fluoride annulation C−H bond cleavage norbornene palladium |
|
