Abstract: | Highly porous interpolymer ion-exchange membranes of poly(styrene sulfonic acid) and poly(vinylidene fluoride) have been investigated under pressure filtration with KCI, Na2SO4, erythrosin, and bovine serum albumin as solutes in the feed solution. The rejection of the ionic solutes is governed by a Donnan exclusion of electrolyte from the membrane phase. A model for the transport behavior is proposed that includes both diffusive and convective salt transport. The calculated rejections agree adequately with the observed data. |