Challenges and Recent Developments of Photoflow-Reversible Deactivation Radical Polymerization (RDRP) |
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Authors: | Zhong Zhuo-Ran Chen Yi-Nan Zhou Yang Chen Mao |
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Institution: | 1.State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200433, China ; |
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Abstract: | Photo-controlled reversible-deactivation radical polymerization(photo-RDRP) has been investigated as a "green" and spatiotemporally controlling pathway for polymer synthesis. While the combination of photo-RDRP and flow chemistry has offered opportunities to increase light intensity and enable uniform light irradiation, problems associated with flow approaches still remain for photoflow-RDRP, which has hindered merging flow polymerization with other cutting-edge techniques. Herein, we summarize challenges and recent achievements in photoflow-RDRP including the development of(a) droplet/slug-flow to regulate residence time distribution,(b) mixing techniques to tailor polymer,(c) polymerization induced self-assembly, and(d) computer-aided synthesis. We hope this work will provide informative knowledge to people in related fields and stimulate novel ideas to promote polymer synthesis in both academia and industry. |
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Keywords: | Controlled radical polymerization RDRP Photopolymerization Flow chemistry Flow polymerization |
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