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Direct determination of interfacial energy between brittle and polymeric films
Authors:T. S. Chow  C. A. Liu  R. C. Penwell
Abstract:Very few analyses exist for determining the adhesion f thin brittle films in the micron range on low modulus polymeric substrates. A theoretical model and experimental means are developed to determine the adhesion for this situation using the concept of fracture mechanics and Griffith's energy criterion. An expression for the adhesion is derived in terms of the external loading, material constants, and thicknesses of the films. The model is compared with measurements of brittle films vacuum deposited onto polymeric substrates. Excellent agreement is obtained and interfacial energies are calculated. Since the moduli of thin films are very difficult to determine accurately, the effect of a variation in measurements of this material parameter on the adhesion is calculated. The effect of varying preparative conditions is also discussed.
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