The effects of conformation on the noncovalent bonding interactions in a bistable donor-acceptor [3]catenane |
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| Authors: | Cheng Wang Dennis Cao Albert C Fahrenbach Sergio Grunder Sanjeev K Dey Amy A Sarjeant J Fraser Stoddart |
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| Institution: | Center for the Chemistry of Integrated Systems, Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA. stoddart@northwestern.edu. |
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| Abstract: | A switchable donor-acceptor bistable 3]catenane, composed of a crown ether containing a pair of alternating π-electron rich tetrathiafulvalene and 1,5-dioxynaphthalene units, encircled by two π-electron deficient cyclobis(paraquat-p-phenylene) rings, has been synthesised and the redox-activated switching it undergoes investigated. |
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