Enantiodivergent synthesis of both enantiomers of gypsy moth pheromone disparlure |
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| Authors: | Prasad Kavirayani R Anbarasan Pazhamalai |
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| Institution: | Department of Organic Chemistry, Indian Institute of Science, Bangalore 560012, India. prasad@orgchem.iisc.ernet.in |
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| Abstract: | Enantiodivergent synthesis of both (-)- and (+)-disparlure, a bioactive pheromone, possessing a cis-epoxide has been accomplished. The key step involves the cross metathesis of a chiral homoallylic alcohol derived from l-(+)-tartaric acid. |
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