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Sorption of 2-naphthol and copper ions by cationic surfactant-adsorbed laponite
Authors:Kunio Esumi  Koji Yoshida  Kanjiro Torigoe  Yoshifumi Koide
Institution:

a Department of Applied Chemistry and Institute of Colloid and Interface Science, Science University of Tokyo, Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan

b Department of Applied Chemistry and Biochemistry, Faculty of Engineering, Kumamoto University, Kurokami, Kumamoto 860-0862, Japan

Abstract:As one of applications of adsolubilization, a simultaneous sorption of 2-naphthol and copper ions by cationic surfactant-adsorbed laponite was carried out. Both the surfactant-adsorbed laponite using dodecyl trimethylammonium bromide (DTAB) and 1,2-bis(dodecyldimethylammonio) ethane dibromide (2RenQ) retained a high sorption capacity for copper ions, while the 2RenQ-adsorbed laponite completely adsolubilized 2-naphthol in a whole concentration region, but the DTAB-adsorbed laponite one decreased the adsolubilization gradually above the cmc of DTAB. Thus, it was found that laponite having cationic surfactant-adsorbed layer has a great capacity for a simultaneous removal of both toxic nonionic and ionic compounds.
Keywords:Laponite  Adsolubilization  2-Naphthol  Copper ion  Cationic surfactant
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