Crystal structure of oxotitanium(IV) 2,2,6,6-tetramethyl-3,5-heptanedionate |
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| Authors: | N. B. Morozova A. E. Turgambaeva I. A. Baidina V. V. Krysyuk I. K. Igumenov |
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| Affiliation: | (1) A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk |
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| Abstract: | The structure of titanyl dipivalylmethanate TiO(dpm)2 has been studied by X-ray diffraction analysis. The compound has a molecular structure formed by isolated centrosymmetrical dimers [TiO(dpm)2]2; the unit cell contains two structurally related, crystallographically unique binuclear molecules. The Ti...Ti distance in the dimer is 2.73 Å. Crystal data for Ti2C36H76O10: a = 32.477(6) Å, b = 14.409(3) Å, c = 25.630(5) Å; β = 107.82(3)°, space group C2/c, Z = 8, d calc = 1.002 g/cm3. |
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| Keywords: | titanyl β -diketonates dipivalylmethanate structure dimer CVD |
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