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Mercury and cadmium pnictidehalides: the inverted Zintl phases
Authors:Shevelkov  A. V.  Shatruk  M. M.
Affiliation:(1) Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899 Moscow, Russian Federation
Abstract:The structures of the mercury and cadmium pnictidehalides MaZbXc (M = Cd, Hg; Z = P, As, Sb; X = Cl, Br, I) are discussed on the basis of the Zintl--Klemm concept. Primary attention is paid to the relationship between the crystal and electronic structures of the compounds in question.
Keywords:Zintl phases  pnictidehalides  crystal structure  solid-state chemistry  cadmium  mercury  pnicogen
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