Thermotropic mesomorphism of soft materials bearing carboxylate-supported mu4-oxo tetracupric clusters |
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| Authors: | Shakya Rajendra Keyes Paul H Heeg Mary Jane Moussawel Azzam Heiney Paul A Verani Claudio N |
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| Affiliation: | Departments of Chemistry and Physics & Astronomy, Wayne State University, Detroit, Michigan 48202, USA. |
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| Abstract: | A new ligand containing long alkyl (octadecyl) chains was used to obtain the mesogenic complex [L2Cu4(mu4-O)(OAc)4].EtOH (1). This complex was thoroughly characterized and had its molecular structure solved by X-ray diffraction (XRD). Mesomorphic properties were demonstrated by means of polarized microscopy, differential scanning calorimetry, and XRD. |
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