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MnF2的高压Raman光谱研究
引用本文:赵永年 樊玉国 等. MnF2的高压Raman光谱研究[J]. 高压物理学报, 1990, 4(1): 1-6
作者姓名:赵永年 樊玉国 等
作者单位:[1]吉林大学原子与分子物理研究所 [2]理论化学研究所
摘    要: 本文首次报道了在0~3.21 GPa压力范围内MnF2的高压Raman光谱,结果表明压力在1.32 GPa附近,MnF2发生了一次结构相变,晶胞中氟原子构成的八面体没有解体。在3.21 GPa下,Raman谱带消失,表明又有一次结构相变发生。

关 键 词:高压  Raman光谱  结构相变
收稿时间:1989-07-22;

STUDIES OF RAMAN SPECTRA FOR MnF_2 AT HIGH-PRESSURES
Zhao Yangnian. Cui Qiliang. Liu Zhenxian,Xu Yiqiu,Fan Yuguo. Zou Guangtian. STUDIES OF RAMAN SPECTRA FOR MnF_2 AT HIGH-PRESSURES[J]. Chinese Journal of High Pressure Physics, 1990, 4(1): 1-6
Authors:Zhao Yangnian. Cui Qiliang. Liu Zhenxian  Xu Yiqiu  Fan Yuguo. Zou Guangtian
Affiliation:1. Institute of Atomic and Molecular Physics, Jilin University, Changchun 130023, China;2. Institute of Theoretic Chemistry, Jilin University, Changchun 130023, China
Abstract:High-pressure Raman spectra of MnF2 are reported Tor the first time. The results show that MnF2 undergoes a structural transition at 1.32GPa, though the octahedron consisting of 8-fluorine atoms in the cell does not disintegrate due to the transition. No Raman peaks can be seen in the spectrum taken at 3.21 GPa,dempnstrating that MnF2 undergoes probably another structure phase transition.
Keywords:high-pressure. Raman spectra   structure phase transition.
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