Enyne ring-closing metathesis on heteroaromatic cations |
| |
Authors: | Núñez Ana Cuadro Ana M Alvarez-Builla Julio Vaquero Juan J |
| |
Affiliation: | Departamento de Química Orgánica. Universidad de Alcalá, 28871-Alcalá de Henares, Madrid, Spain. |
| |
Abstract: | Cationic heteroaromatic enynes have been employed as substrates in enyne ring-closing metathesis, under an atmosphere of ethylene and using the Hoveyda-Grubbs catalyst, for the first time; the reaction affords new 1-vinyl- and 2-vinyl-substituted 3,4-dihydroquinolizinium salts, useful precursors for biologically relevant cations based on the quinolinizium system. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|