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PREPARATION AND PROPERTIES OF SILICONE-ACRYLATE COPOLYMER LATEX
作者姓名:Mu-jieYang  WeiZhang
作者单位:DepartmentofPolymerScienceandEngineering,ZhejiangUniversity;Hangzhou310027,China
摘    要:Silicone-acrylate copolymer latex was prepared through three different polymerization processes, i.e., the batch process, preemulsified monomer addition and the monomer addition process. The results revealed that the monomer addition process is a desirable approach to produce narrow particle size distribution latex with higher polymerization conversion and less amount of coagulum. The effect of silicone content on the glossiness and water absorption of latex film was investigated and the results showed that the glossiness of latex film is improved up to a silicone content of 10% of total monomers, but becomes impaired thereafter, whereas water absorption is reduced accordingly.

关 键 词:硅树脂-丙烯酸酯共聚乳剂  聚合变换  水吸附  胶乳膜性质  制备
收稿时间:2003-01-03
修稿时间:2003-02-27

PREPARATION AND PROPERTIES OF SILICONE-ACRYLATE COPOLYMER LATEX
Mu-jieYang WeiZhang.PREPARATION AND PROPERTIES OF SILICONE-ACRYLATE COPOLYMER LATEX[J].Chinese Journal of Polymer Science,2004,0(3):215-218.
Authors:Mu-jie Yang  Wei Zhang
Institution:Department of Polymer Science and Engineering, Zhejiang University; Hangzhou 310027, China
Abstract:Silicone-acrylate copolymer latex was prepared through three different polymerization processes, i.e., the batch process, preemulsified monomer addition and the monomer addition process. The results revealed that the monomer addition process is a desirable approach to produce narrow particle size distribution latex with higher polymerization conversion and less amount of coagulum. The effect of silicone content on the glossiness and water absorption of latex film was investigated and the results showed that the glossiness of latex film is improved up to a silicone content of 10% of total monomers, but becomes impaired thereafter, whereas water absorption is reduced accordingly.
Keywords:Silicone-acrylate latex  Polymerization conversion  Latex film properties  Water absorption  LATEX  COPOLYMER  PROPERTIES  impaired  effect  water absorption  film  improved  silicone  content  total  results  approach  narrow  particle size distribution  polymerization conversion  monomer  addition  batch process  copolymer
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