| Studies on sulfinatodehalogenation ⅩⅩⅣ.Further study on sodium dithionite-initiated perfluoroalkylation of electron-rich aromatics |
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| 基金项目： | the National Natural Science Foundation of China.Part ⅩⅩⅢ in this series,see Huang,W.-Y.，Zhuang,J.-L.,Chinese J.Chem.,9,270 (1991). |
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| 摘 要： | The application ot the sulfinatodehalogenation reaction system for the perfluoroalkylationof electron-rich aromatics is further studied.It was shown that perfluoroalkyl iodides reacted withpolyhydric phenols,N,N-dialkylanilines,2,5-dimethylpyrrole,N-methylpyrrole initiated by Na_2S_2O_4-NaHCO_3 gave the corresponding perfluoroalkylated products in moderate to good yields.
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