<Emphasis Type="Italic">N</Emphasis>-(2-chloro-1,2-difluorovinyl) derivatives of azoles |
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Authors: | K I Petko S Yu Kot L M Yagupol’skii |
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Institution: | 1.Institute of Organic Chemistry,National Academy of Sciences of Ukraine,Kiev,Ukraine |
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Abstract: | Reactions of N-(2,2-dichloro-1,1,2-trifluoroethyl)-substituted azoles with zinc, magnesium, butyllithium, and tris(diethylamino)phosphine
were studied, and optimal conditions for the preparation of the corresponding N-(2-chloro-1,2-difluorovinyl) derivatives were found tris(diethylamino)phosphine, chlorotrimethylsilane]. Some reactions
of the obtained unsaturated fluorinated compounds with sulfur-centered nucleophiles were examined. |
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