| 基于8-羟基喹啉与d10金属原位合成的双核配合物的合成、晶体结构及其光致发光性质 |
| |
| 引用本文： | 高翔,徐微,吴昌丽,朱锡淼,区泳聪,吴建中. 基于8-羟基喹啉与d10金属原位合成的双核配合物的合成、晶体结构及其光致发光性质[J]. 无机化学学报, 2018, 34(9): 1768-1774 |
| |
| 作者姓名： | 高翔 徐微 吴昌丽 朱锡淼 区泳聪 吴建中 |
| |
| 作者单位： | 华南师范大学化学与环境学院广州市能源转化与储能材料重点实验室 |
| |
| 基金项目： | 国家自然科学基金（No.21401058）和华南师范大学青年教师培育基金项目（No.16KJ20）资助 |
| |
| 摘 要： | 利用8-羟基喹啉原位反应,通过溶剂热方法制备出3种新颖的d~(10)配合物[M_2(HL)_3]NO_3·H_2O (M=Cd (1),Zn (2,3)),H_2L为1,1-(7,7′-二-(8-羟基喹啉))。单晶结构表明,3种配合物有着相同的带正电荷的结构单元[M_2(HL)_3]~+,但由于客体分子所处空间位置的不同表现为不同的空间结构,配合物1和3结晶于六方晶系(P6_3/m),配合物2结晶于三方晶系(R3)。中心金属离子以六配位的模式与来自HL-配体上的3个氧原子和3个氮原子形成一个轻微扭曲的八面体几何构型。存在于HL-配体与客体分子(NO_3~-,H_2O)间大量的弱作用力在结构空间堆积上起到了重要的作用。3种配合物均具有良好的热稳定性和绿色荧光发射性质。同时,通过从配合物1中提取出原位生成的配体H_2L,首次报道了其蓝色荧光发射性质。
|
| 关 键 词： | d10配合物 原位反应 晶体结构 弱作用 荧光性质 |
| 收稿时间： | 2018-05-25 |
| 修稿时间： | 2018-06-17 |
Syntheses, Crystal Structures and Luminescent Properties of Dinuclear d10 Complexes Based on a Ligand Formed in Situ by 8-Hydroxyquinoline |
| |
| GAO Xiang,XU Wei,WU Chang-Li,ZHU Xi-Miao,OU Yong-Cong and WU Jian-Zhong. Syntheses, Crystal Structures and Luminescent Properties of Dinuclear d10 Complexes Based on a Ligand Formed in Situ by 8-Hydroxyquinoline[J]. Chinese Journal of Inorganic Chemistry, 2018, 34(9): 1768-1774 |
| |
| Authors: | GAO Xiang XU Wei WU Chang-Li ZHU Xi-Miao OU Yong-Cong WU Jian-Zhong |
| |
| Affiliation: | Guangzhou Key Laboratory of Materials for Energy Conversion and Storage, School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China,Guangzhou Key Laboratory of Materials for Energy Conversion and Storage, School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China,Guangzhou Key Laboratory of Materials for Energy Conversion and Storage, School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China,Guangzhou Key Laboratory of Materials for Energy Conversion and Storage, School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China,Guangzhou Key Laboratory of Materials for Energy Conversion and Storage, School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China and Guangzhou Key Laboratory of Materials for Energy Conversion and Storage, School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China |
| |
| Abstract: | Three novel d10 complexes[M2(HL)3] NO3·H2O (M=Cd (1), Zn (2, 3), H2L=7,7''-(ethane-1,1-diyl)diquinolin-8-ol) have been synthesized under solvothermal conditions. Single crystal X-ray diffraction analysis reveals that the complexes have the same coordination positive charged unit,[M2(HL)3]+, but different lattice structures due to the different places of the guest molecules. Complexes 1 and 3 crystallize in hexagonal system (P63/m) and complex 2 crystallizes in trigonal system (R3). The metal ions are six-coordinated with three oxygen atoms and three nitrogen atoms of three HL- ligands, presenting a slightly distorted octahedron geometry. There are abundant weak interactions between HL- ligands and guest molecule (NO3- and H2O), which play a vital role in the form of the crystal packing. These complexes show good thermal stabilities and exhibit green fluorescence. Further, the fluorescence of ligand H2L extracted from the complex 1 has also been studied firstly and blue light emission of it was observed. |
| |
| Keywords: | d10 complexes in situ reaction crystal structures weak interaction luminescent properties |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
|
点击此处可从《无机化学学报》下载全文 |
|
