| 含茂基、烷氧基及氯离子混合配镧系金属有机化合物的合成及表征 |
| |
| 引用本文： | 吴忠志,徐正,吴红英,周昔庚. 含茂基、烷氧基及氯离子混合配镧系金属有机化合物的合成及表征[J]. 无机化学学报, 1993, 9(4): 352-356 |
| |
| 作者姓名： | 吴忠志 徐正 吴红英 周昔庚 |
| |
| 作者单位： | 南京大学配位化学研究所，中国科学技术大学结构分析开放实验室，内蒙古师范大学化学系，安徽师范大学有机化学研究所 南京210008，合肥230026，芜湖241000 |
| |
| 基金项目： | 国家自然科学基金资助项目 |
| |
| 摘 要： | 本文通过二茂基镧不金属氯化物Ｃｐ２ＬｎＣｌ（Ｃｐ＝Ｃ５Ｈ５；Ｌｎ＝Ｄｙ，Ｙｂ）与烷基醇ＲＯＨ（Ｒ＝－ＣＨ２ＣＨ２ＣＨ３，－ＣＨ２ＣＨ＝ＣＨ２）在四氢呋喃中反应，合成了四个新的含三种不同配位基的镧系金属有机化合物；元素分析，红外光谱及质谱分析表明这些化合物可能具有三聚体结构，即：［ＣｐＬｎ（ＯＲ）Ｃｌ］３。
|
| 关 键 词： | 镧系 金属有机化物 配位化合物 |
| 收稿时间： | 1992-07-02 |
SYNTHESIS AND CHARACTERIZATION OF MIXED LIGAND ORGANOLANTHANIDE COMPOUNDS INVOLVING CYCLOPENTADIENYL, ALKOXIDE AND CHLORIDE ANION LIGANDS |
| |
| Wu Zhongzhi,Xu Zheng,Wu Hongying and Zhou Xigeng. SYNTHESIS AND CHARACTERIZATION OF MIXED LIGAND ORGANOLANTHANIDE COMPOUNDS INVOLVING CYCLOPENTADIENYL, ALKOXIDE AND CHLORIDE ANION LIGANDS[J]. Chinese Journal of Inorganic Chemistry, 1993, 9(4): 352-356 |
| |
| Authors: | Wu Zhongzhi Xu Zheng Wu Hongying Zhou Xigeng |
| |
| Affiliation: | Coordination Chemistry Institute, Nanjing University, Nanjing 210008;Structural Laboratory of Analytical Center, University of Science and Technology of China, Hefei 230026,Coordination Chemistry Institute, Nanjing University, Nanjing 210008;Structural Laboratory of Analytical Center, University of Science and Technology of China, Hefei 230026,Coordination Chemistry Institute, Nanjing University, Nanjing 210008;Structural Laboratory of Analytical Center, University of Science and Technology of China, Hefei 230026 and Institute of Organic Chemistry, Anhui Normal University, Wuhu 241000 |
| |
| Abstract: | By reaction of Cp2LnCl(Cp = C5H5; Ln = Dy, Yb) with ROH(R = -CH2CH2CH3, -CH2CH = CH2) in THF (tctrahydrofuran) at room temperature, four new mixed ligand organolanthanidc compounds involving three different ligands (namely, cyclopcntadienyl, alkoxidc and chloride anion) have been synthesized. All the compounds were characterized by elemental analysis, infrared and mass spectra, indicating that they are possibly trimeric. Their general formula is [CpLn(OR)Cl]3. |
| |
| Keywords: | organolanthanide compound cyclopentadienyl alkoxide chloride mixed ligand compound synthesis characterization |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
|
点击此处可从《无机化学学报》下载全文 |
|
