Kinetics of oxidation of octacyanomolybdate(V) ion by thiosulfate |
| |
| Authors: | G J Lamprecht J G Leipoldt C R Dennis and S S Basson |
| |
| Institution: | (1) Department of Chemistry, University of the Orange Free State, 9300 Bloemfontein, Republic of South Africa |
| |
| Abstract: | The oxidation of thiosulfate by octacyanomolybdate(V) in the pH range of 4,0 to 5,1 is catalyzed by alkali metal ions and shows first order dependence on the concentrations of thiosulfate, octacyanomolybdate(V) and alkali metal ions and is independent of the hydrogen ion concentration. A mechanism for the reaction is proposed.
                 (V)  pH=4,0–5,1        .     , (V) .  .  .
|
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
