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Determinations of the transient thermal lensing effect in metal cluster Polymer {WS4Cu4I2(bpe)3}n solution by the use of the Z-scan
Authors:Junyi Yang  Jihua Gu
Institution:a School of Physical Science and Technology, Suzhou University, Suzhou 215006, PR China
b State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093, PR China
Abstract:The nonlinear optical (NLO) properties of a novel cluster Polymer {WS4Cu4I2(bpe)3}n solution are studied by using Z-scan technique with laser pulses of 4.5 ns pulse-width at a wavelength of 532 nm. The results show that the cluster solution possesses strong nonlinear absorption and refraction. Nonlinear refraction of the cluster is composed of third-order nonlinear refraction and transient thermal effect. The thermal effect is mainly due to the strong nonlinear absorption. Numerical simulations obtained by solving simultaneously photo-acoustic and electromagnetic wave equations, agrees basically with experimental results.
Keywords:78  66  Qn  42  65  Hw  78  20  Nv
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