Biomimetic total synthesis of cruentaren A via aromatization of diketodioxinones |
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| Authors: | Fouché Marianne Rooney Lisa Barrett Anthony G M |
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| Institution: | Department of Chemistry, Imperial College, London SW7 2AZ, England. |
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| Abstract: | The total synthesis of cruentaren A, a biologically active resorcylate natural product, is reported. The aromatic unit was constructed via late-stage cyclization and aromatization from a diketodioxinone intermediate and macrocyclization using Fürstner ring-closing alkyne metathesis. |
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