| 含氮或碳中心原子的窝穴体开链类似物的合成与研究 |
| |
| 引用本文： | 黎其万,刘复初.含氮或碳中心原子的窝穴体开链类似物的合成与研究[J].有机化学,1995,15(4):360-364. |
| |
| 作者姓名： | 黎其万 刘复初 |
| |
| 作者单位： | 云南大学化学系 云南(黎其万)，云南大学化学系 昆明(刘复初) |
| |
| 摘 要： | 本文合成了十种含氮或碳中心原子的窝穴体开链类似物(1a～e, 2a～e). 通过三乙醇胺, 季戊四醇及4-羟基安替比林的O-烷基化和用季戊四溴对2-巯基苯并咪唑, 2-巯基苯并噻唑的S-烷基化方法. 以它们作为液膜(CHCl~3)离子载体对Ag(I)迁移实验表明, 化合物1a～e迁移能力较强.
|
| 关 键 词： | 合成 烷基化 迁移性 离子载体 窝穴体开链类似物 |
Syntheses and studies of open chain analogues of cryptands with nitrogen or carbon as central atom |
| |
| LI Chi-Wan,LIU Fu-Chu.Syntheses and studies of open chain analogues of cryptands with nitrogen or carbon as central atom[J].Chinese Journal of Organic Chemistry,1995,15(4):360-364. |
| |
| Authors: | LI Chi-Wan LIU Fu-Chu |
| |
| Abstract: | Ten open chain analogues with nitrogen or carbon as central atom (1a-e, 2a-e) were synthesized through O-alkylation of trithanoiamme, pentaerythritol and 4-hydroxy-antipyrine and S-alkylation of 2-mercaptobenzimidazole and 2-mercaptobenzothiazole with pentaerythrityltetrabromide. Their activities as ion transport carrier of Ag(I) in liquid membrane (CHCl3) have been studied. It has been found that compounds 1a-e have good transport activity for Ag(I). |
| |
| Keywords: | open chain analogues of cryptand O-alkylation S-alkylation ion transport carrier synthesis |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《有机化学》浏览原始摘要信息 |
| 点击此处可从《有机化学》下载免费的PDF全文 |
