| 全氟丁基取代烯烃的制备及其硼氢化反应 |
| |
| 引用本文： | 荣国斌.全氟丁基取代烯烃的制备及其硼氢化反应[J].有机化学,1995,15(4):370-375. |
| |
| 作者姓名： | 荣国斌 |
| |
| 作者单位： | 华东理工大学化学系 上海 |
| |
| 摘 要： | 在相转移催化或超声作用下, 全氟丁基碘和烯烃或炔烃发生加成反应, 从加成得到的烷烃脱碘化氢或烯烃加成产物脱碘还原生成全氟丁基取代烯烃. 全氟丁基取代烯烃的硼氢化反应主要得到α-全氟丁基取代的硼烷.
|
| 关 键 词： | 合成 硼氢化作用 全氟烯烃 |
The preparation and hydrobration reaction of perfluorobuty substituted alkenes |
| |
| RONG Guo-Bin.The preparation and hydrobration reaction of perfluorobuty substituted alkenes[J].Chinese Journal of Organic Chemistry,1995,15(4):370-375. |
| |
| Authors: | RONG Guo-Bin |
| |
| Abstract: | Addition of perfluorobutyl iodide to C-C multiple bond is efficiently achieved by Na~2S~2O~4 in phase transfer of ultrasonic irradiation condition . The perfluorobutyl alkenes are produce from the β-iodoperfluorobutyl alkanes by elimination of hydrogen iodide or from β-iodoperfluorobutyl alkenes by deiodoreduction. The gydrovoration reaction of perfluorovutyl alkenes were also studied. |
| |
| Keywords: | perfluorobutyl substituted olefins hydroboration reaction synthesis |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《有机化学》浏览原始摘要信息 |
| 点击此处可从《有机化学》下载免费的PDF全文 |
