| 聚苯乙烯-二苯基膦-铜(Ⅰ)-四氢化硼络合物的制备及其对酰氯的还原 |
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| 引用本文： | 熊桂荣,黄锦霞,张万轩,陈家威. 聚苯乙烯-二苯基膦-铜(Ⅰ)-四氢化硼络合物的制备及其对酰氯的还原[J]. 有机化学, 1995, 15(6): 622-626 |
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| 作者姓名： | 熊桂荣 黄锦霞 张万轩 陈家威 |
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| 作者单位： | 武汉市乡镇企业管理局科技处;湖北大学化学系 |
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| 摘 要： | 以不同交联度(1%, 2%, 4%, 7%, 8%, 12%)的聚苯乙烯树脂为支载体, 制备了聚苯乙烯-二苯基膦-铜-四氢化硼络合物, 对它们的容量和结构进行了测试和分析, 并研究了该络合物在不同温度、溶剂、催化剂下, 对苯甲酰氯, 肉桂酰氯, 对硝基苯甲酰氯的还原性能以及其回收再生后的重复使用情况。
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| 关 键 词： | 红外分光光度法 高速液体色谱 聚苯乙烯 酰氯 铜络合物 二苯基膦 还原剂 四氢化硼 |
Preparation of polystyryl diphenyl phosphine copper(Ⅰ) tetrahydroborate and reduction of acyl chloride |
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| Abstract: | A few polystyryl diphenyl copper(Ⅰ) Tetrahydroborate complexes (PDPCT) were prepared using various crosslinking (1%, 2%, 4%, 7%, 8%, 12%) polystyrene beads as supports. Their contents and structures were tested and analyzed, which their behavior reducing benzoyl chlo-ride, cinnamoyl chloride, p-nitrobenzoyl chloride to the corresponding aldehydes or alcohols in the different conditions of temperature, solvent and catalyst and recovering were studied. |
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| Keywords: | INFRARED SPECTROPHOTOMETRY HIGH SPEED LIQUID CHROMATOGRAPHY POLYSTYRENE ACYL CHLORIDES COPPER COMPLEX DIPHENYLPHOSPHINE REDUCER |
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