| 测定梭曼四种立体异构体的NMR研究 |
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| 引用本文： | 缪振春,杜泽涵.测定梭曼四种立体异构体的NMR研究[J].波谱学杂志,1989,6(4):469-472. |
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| 作者姓名： | 缪振春 杜泽涵 |
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| 作者单位： | 军事医学科学院, 北京 |
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| 摘 要： | 本文采用手性位移试剂、Eu(TFC)和Eu(HFC)3对梭曼的立体异构体测定作了研究.结果表明,在苯中梭曼的立体异构体与其中的Eu(HFC)3形成的络合物显示较大的19F化学位移差,并能同时进行测定.该法尚未见报道.
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| 关 键 词： | 梭曼 异构体 乙酰胆碱酯酶 抑制剂 |
| 收稿时间： | 1988-06-03 |
NMR STUDY ON DETERMINATION OF THE FOUR STEREOISOMERS OF SOMAN |
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| Miao Zhenchun,Du Zehan.NMR STUDY ON DETERMINATION OF THE FOUR STEREOISOMERS OF SOMAN[J].Chinese Journal of Magnetic Resonance,1989,6(4):469-472. |
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| Authors: | Miao Zhenchun Du Zehan |
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| Institution: | Academy of Military Medical Sciences, Beijing |
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| Abstract: | The dctermina of four of soman has been studied by NMR chiral shift reagents Eu (TFC)3 and Eu (MFC)3. It was found that the complexes of soman with Eu (HFC)3 in C6D6 show larger 19F NMR shift difference, which can been used for the simultaneous qantitaivc determination of the four stcrcoisomcrs of soman. |
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