| 棉酚及其衍生物在溶剂中的氢转移 |
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| 引用本文： | 杨薇蔓 施孝迂. 棉酚及其衍生物在溶剂中的氢转移[J]. 波谱学杂志, 1989, 6(2): 209-220 |
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| 作者姓名： | 杨薇蔓 施孝迂 |
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| 作者单位： | 中国科学院兰州化学物理研究所(杨薇蔓，施孝迂，杨天香，成永泰)，无锡轻工业学院(刘复光) |
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| 摘 要： | 本文利用~1HNMR法研究棉酚及其胺类衍生物(双苯胺棉酚,双丁基棉酚和双嘧啶棉酚)在不同溶剂(CDCl_3,DMSO-d_6,C_6D_6,CD_3COCD_3,DMF-d_7 等)中和不同的酸碱环境下的氢转移(即结构互交).实验表明,棉酚、双苯胺棉酚、双丁基棉酚和双嘧啶存在着三种不同的异构体.这些异构体在同一溶剂不同环境下可以并存或者相互转变.
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| 关 键 词： | 核磁共振 棉酚 氢转移 异构体 |
THE HYDROGEN TRANSFER OF GOSSYPOL AND ITS DERIVATIVES IN DIFFERENT SOLVENTS |
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| Yang Weiman Shi Xiaoyu Yang Tianxiang and Cheng Yongtai. THE HYDROGEN TRANSFER OF GOSSYPOL AND ITS DERIVATIVES IN DIFFERENT SOLVENTS[J]. Chinese Journal of Magnetic Resonance, 1989, 6(2): 209-220 |
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| Authors: | Yang Weiman Shi Xiaoyu Yang Tianxiang and Cheng Yongtai |
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| Abstract: | In this paper, the hydrogen transfer of gossypol and its imino derivatives (dianilinogossypol , dipyrimidinyliminogossypol and di-n-butyliminogossypol ) in various solvents ( CDCl3,DMSO -d6,D6CD3COCD3and DMF-d7) under different acidic or basic conditions was shudicd by 1H NMR method . Results show that , three different tautomers existed for each of the above mentioned gossypol imino derivatives , Moreover , the forms of these three tautomcrs are interchangable or co-exist in the same solvent under different conditions . |
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| Keywords: | NMR Gossypol Hydrogen Transfer Tautomcr |
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