| 一些Fe-Mo(W)-S双金属化合物的1H-NMR研究 |
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| 引用本文： | 吴达旭,郭智.一些Fe-Mo(W)-S双金属化合物的1H-NMR研究[J].波谱学杂志,1989,6(1):111-114. |
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| 作者姓名： | 吴达旭 郭智 |
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| 作者单位： | 中国科学院福建物质结构研究所 |
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| 摘 要： | 本文对六种双金属化合物Et4N]2(PhS)2FeS2MS2-nOn](M=Mo,W;n=0,1,2,)的1H-NMR作了研究,表明各向同性位移主要来自接触位移的作用,其值大小与Fe→M电荷迁移密切相关.
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| 关 键 词： | 核磁共振波谱 穆斯堡尔波谱 |
| 收稿时间： | 1987-12-12 |
~1H-NMR STUDIES OF SOME Fe-Mo (W) -S DEMETALLIC COMPOUNDS |
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| Wu Daxu Gou Zhi,Liu Hanqjn.~1H-NMR STUDIES OF SOME Fe-Mo (W) -S DEMETALLIC COMPOUNDS[J].Chinese Journal of Magnetic Resonance,1989,6(1):111-114. |
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| Authors: | Wu Daxu Gou Zhi Liu Hanqjn |
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| Institution: | Fujian Institute of Research on the Structure of Matter, Academia Sinica, Fuzhou, Fujian |
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| Abstract: | Six dimetallic compounds (Et4N)2((PhS)2FeS2MS2-nOn (M=Mo,W; n=0, 1, 2) were studied by 1H-NMR. These results indicate that the isotropic shift is dominantly from contact interaction. Its magnitudes are correlated closely with Fe→M charge transfer which relies on the type of metal M and ite environment. |
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| Keywords: | NMR Mossbauer |
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