| 苷类化合物研究Ⅱ——熊果苷和天麻苷类似物的NMR研究 |
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| 引用本文： | 李立璞,彭师奇.苷类化合物研究Ⅱ——熊果苷和天麻苷类似物的NMR研究[J].波谱学杂志,1989,6(1):1-7. |
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| 作者姓名： | 李立璞 彭师奇 |
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| 作者单位： | 1. 中国科学院化学研究所;2. 北京医科大学 |
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| 摘 要： | 本文用NMR的1H谱和13C谱确定了一系列万同取代基的熊果苷类似物和天麻苷类似物的结构,研究了熊果苷类似物的端基构型,指出了不同构型图谱的特征,用所得的结论推断出天麻苷类似物的端基构型为β型.
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| 关 键 词： | 熊果苷 天麻苷 端基构型 NMR |
| 收稿时间： | 1986-12-20 |
THE STUDY ON NMR OF DERIVATIVES OF ARBUTIN AND GASTRODIN |
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| Li Lipu,Peng Shiqi,Wu Jianwei,Cai Mengshen.THE STUDY ON NMR OF DERIVATIVES OF ARBUTIN AND GASTRODIN[J].Chinese Journal of Magnetic Resonance,1989,6(1):1-7. |
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| Authors: | Li Lipu Peng Shiqi Wu Jianwei Cai Mengshen |
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| Institution: | 1. Institute of Chemistry, Academe Sinica, Beijing;2. College of Pharmaceutical Sciences, Beijing Medical University, Beijing |
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| Abstract: | The 1H NMR and 13C NMR of arbutin, gastrodin and their derivatives were studied. The configurations of arbutin and their derivatives were assigned based on 1H NMR and 13C NMR date of these compounds. The feature of the spectra of various configurations were indicated. We colud deduce that the configurations of gastrodin was β isomer from the obtained conclusion. |
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| Keywords: | arbutin gastrodin anomeric configuration NMR |
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