Preparation and reactivity of metal-containing monomers |
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| Authors: | I. I. Zheltvai T. I. Movchan I. S. Voloshanovskii A. D. Pomogailo |
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| Affiliation: | (1) A. V. Bogatskii Physico-Chemical Institute of the Ukrainian Academy of Sciences, 80 ul. Chernomorskaya doroga, 270086 Odessa, Ukraine;(2) Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, Chernogolovka, 142432 Moscow Region, Russian Federation |
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| Abstract: | The stability of chelates of several bivalent metals with poly(methacryloylacetone) was determined by pH titration. Two models in which the fragment of a polymeric molecule in the coordination sphere of a metal was approximated by either a mono- or a bidentate ligand were considered. Different mechanisms of complex formnation were realized depending on the nature of M(II).For part 29 seeIzv. Akad. Nauk, Ser. Khim., 1993, 975 [Russ. Chem. Bull., 1993,42, 937 (Eng.Transl.)].Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1063–1066, June, 1993. |
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| Keywords: | pH titration complexation stability constants of chelates poly(methacryloylacetone) |
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