| Energy-transfer Process Accelerated by the Formation of Electrostatically Stabilized Aggregate (ESAg) |
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| 作者姓名： | Xi Kui JIANG* Jian She WANG Ji Liang SHI Shanghai Institute of Organic Chemistry Chinese Academy of Sciences Shanghai |
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| 作者单位： | Xi Kui JIANG*，Jian She WANG，Ji Liang SHI Shanghai Institute of Organic Chemistry，Chinese Academy of Sciences，Shanghai 200032 |
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| 摘 要： | We have proposed that oppositely-charged long-chain molecules with roughly eight to sixteen carbons might form electrostatically stabilized aggregates (ESAgs) by both the hydrophobic-lipophilic interaction (HLI) and the electrostatically attractive force in the concentration range of 10-7 mol/L to 10-5 mol/L1,2. Thus ESAg is yet another structural niche for molecular assemblages in-between the simple aggregate and the micelles. That ESAg species existing at concentrations much lower tha…
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Energy-transfer Process Accelerated by the Formation of Electrostatically Stabilized Aggregate (ESAg) |
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| Xi Kui JIANG*,Jian She WANG,Ji Liang SHI Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai .Energy-transfer Process Accelerated by the Formation of Electrostatically Stabilized Aggregate (ESAg)[J].Chinese Chemical Letters,2001(10). |
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| Authors: | Xi Kui JIANG Jian She WANG Ji Liang SHI |
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| Institution: | Xi Kui JIANG*,Jian She WANG,Ji Liang SHI Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032 |
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| Abstract: | The energy-transfer process between sodium w-2-(a-naphthyl)ethoxy]undecanoate (FP-)* and sodium w-9-anthrylmethyl glutarate (AFP-) is accelerated by the formation of ESAg when cetyltrimethylammonium chloride (S16+) has been added to the solvent system of FP-* and AFP-. This result is yet another evidence for the formation of ESAg . |
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| Keywords: | Energy-transfer process fluorescence spectra ESAg |
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