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Energy-transfer Process Accelerated by the Formation of Electrostatically Stabilized Aggregate (ESAg)
作者姓名:Xi Kui JIANG*  Jian She WANG  Ji Liang SHI Shanghai Institute of Organic Chemistry  Chinese Academy of Sciences  Shanghai
作者单位:Xi Kui JIANG*,Jian She WANG,Ji Liang SHI Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032
摘    要:We have proposed that oppositely-charged long-chain molecules with roughly eight to sixteen carbons might form electrostatically stabilized aggregates (ESAgs) by both the hydrophobic-lipophilic interaction (HLI) and the electrostatically attractive force in the concentration range of 10-7 mol/L to 10-5 mol/L1,2. Thus ESAg is yet another structural niche for molecular assemblages in-between the simple aggregate and the micelles. That ESAg species existing at concentrations much lower tha…


Energy-transfer Process Accelerated by the Formation of Electrostatically Stabilized Aggregate (ESAg)
Xi Kui JIANG*,Jian She WANG,Ji Liang SHI Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai .Energy-transfer Process Accelerated by the Formation of Electrostatically Stabilized Aggregate (ESAg)[J].Chinese Chemical Letters,2001(10).
Authors:Xi Kui JIANG  Jian She WANG  Ji Liang SHI
Institution:Xi Kui JIANG*,Jian She WANG,Ji Liang SHI Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032
Abstract:The energy-transfer process between sodium w-2-(a-naphthyl)ethoxy]undecanoate (FP-)* and sodium w-9-anthrylmethyl glutarate (AFP-) is accelerated by the formation of ESAg when cetyltrimethylammonium chloride (S16+) has been added to the solvent system of FP-* and AFP-. This result is yet another evidence for the formation of ESAg .
Keywords:Energy-transfer process  fluorescence spectra  ESAg  
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