| 开链冠醚类似物的合成与研究I |
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| 引用本文： | 刘建平,刘复初,赵雁来. 开链冠醚类似物的合成与研究I[J]. 化学学报, 1987, 45(6): 606-608 |
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| 作者姓名： | 刘建平 刘复初 赵雁来 |
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| 作者单位： | 云南大学化学系 |
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| 摘 要： |
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| 关 键 词： | 应用 硫酮 冠式化合物 醚 相转移催化 吡唑酮P 交换反应 ＶＩＩＡ族元素 |
Syntheses and studies of open-chain crown ether analogues I |
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| LIU JIANPING,LIU FUCHU,ZHAO YANLAI. Syntheses and studies of open-chain crown ether analogues I[J]. Acta Chimica Sinica, 1987, 45(6): 606-608 |
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| Authors: | LIU JIANPING LIU FUCHU ZHAO YANLAI |
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| Abstract: | Antipyrine derivatives I (Z = O, S; Z1 = CH2, CH2OCH2; n = 0, 1, 2, 3) were prepared as open-chain crown ether analogs. Thus, refluxing diethylene glycol ditosylate with 4-hydroxyantipyrine and K2CO3 in acetone for 15 h gave I (Z = O, Z1 = CH2OCH2). The activities of I as phase-transfer catalyst for iodination of 1-bromoctane with NaI, or KI were reported. |
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| Keywords: | APPLICATION THIOKETONE CROWN ETHER COMPOUNDS ETHER PHASE TRANSFER CATALYSIS PYRAZOLONE P EXCHANGE REACTION GROUP VIIA ELEMENT |
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