Perylene synthesis by the parallel cycloaromatization of adjacent enediynes |
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| Authors: | Chow Palmer Bowles Anthony |
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| Affiliation: | Department of Chemistry, University of Kentucky, Lexington 40506-0055, USA. |
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| Abstract: | As part of an investigation into new synthetic routes to poly(peri-naphthalene), the synthesis and cycloaromatization of tetraethynylbiphenyls is described. The temperature-dependent cyclization of biphenyls containing unsubstituted alkynes provides the desired perylene in good yield. |
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