Theory of the Zeeman effect in doublet states of a near-symmetric rotor: Application to the A2 ← B1 transition of ClO2 |
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| Authors: | J.C.D Brand A.M GarciaC di Lauro |
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| Affiliation: | Department of Chemistry, University of Western Ontario, London, Ontario Canada |
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| Abstract: | Matrix elements of the Hamiltonian for doublet states of rotating molecules in a Zeeman field are calculated in the uncoupled (J, S) representation. The energy matrix assumes a simple form for near-symmetric rotors, when the magnetic interactions are diagonal in K. |
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