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Third-order potential constants and dipole moment of SeO2 by microwave spectroscopy
Authors:Harutoshi Takeo
Institution:Department of Chemistry, Rice University, Houston, Texas 77001 USA; Department of Chemistry, Faculty of Science, Kyushu University, Fukuoka, Japan; Sagami Chemical Research Center, Sagamihara, Kanagawa, Japan
Abstract:The third-order potential constants of SeO2 have been recalculated using the vibrational frequencies reported for matrix-isolated SeO2. General trends of the constants are in good accord with the results obtained for other triatomic molecules, such as SO2, O3, and OF2. The dipole moment was measured more accurately to be 2.62 ± 0.05 D.
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