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Spectral manifestations of nonradiative processes in azulene
Authors:Robin M Hochstrasser  Ta-Yuen Li
Institution:1. Department of Chemistry, The University of Pennsylvania Philadelphia, Pennsylvania 19104 USA;2. Laboratory for Research on the Structure of Matter, The University of Pennsylvania Philadelphia, Pennsylvania 19104 USA
Abstract:The linewidths for S1S0 (at 14 652 cm−1) and S2S0 (at 28 048 cm−1) of azulene in a naphthalene host crystal at 1.2°K are presented along with measurements of the line narrowing due to perdeuteration of the azulene. The results are related to current ideas of nonradiative processes in azulene and azulene-d8.
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