Spectral manifestations of nonradiative processes in azulene |
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Authors: | Robin M Hochstrasser Ta-Yuen Li |
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Institution: | 1. Department of Chemistry, The University of Pennsylvania Philadelphia, Pennsylvania 19104 USA;2. Laboratory for Research on the Structure of Matter, The University of Pennsylvania Philadelphia, Pennsylvania 19104 USA |
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Abstract: | The linewidths for S1 ← S0 (at 14 652 cm−1) and S2 ← S0 (at 28 048 cm−1) of azulene in a naphthalene host crystal at 1.2°K are presented along with measurements of the line narrowing due to perdeuteration of the azulene. The results are related to current ideas of nonradiative processes in azulene and azulene-d8. |
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