Molecular constants of substituted ethylene-type molecules: IV. Inertia defects and rotational constants of vinyl halides and their deuterated derivatives |
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Authors: | S. JeyapandianG.A.Savari Raj |
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Affiliation: | Department of Physics, St. Joseph''s College, Tiruchirapalli-2, University of Madras, Tamil Nadu State(SouthIndia |
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Abstract: | The inertia defects of some vinyl halides and their deuterated derivatives have been calculated on the basis of the general formulation developed by Oka and Morino. The initial sets of Urey-Bradley force constants, based on published data, were adjusted by a least squares procedure until they reproduced the fundamental vibrational frequencies satisfactorily. The Coriolis coupling constants which satisfy the sum rules derived were evaluated and used to calculate the inertia defect in the ground vibrational state. The theoretical values of the inertia defect are used to determine the rotational constant A which cannot otherwise be accurately determined from an “a” type transition. |
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