The total synthesis of spectinabilin and its biomimetic conversion to SNF4435C and SNF4435D |
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Authors: | Jacobsen Mikkel F Moses John E Adlington Robert M Baldwin Jack E |
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Affiliation: | Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford, OX1 3TA, United Kingdom. |
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Abstract: | [reaction: see text] A short synthesis of (+/-)-spectinabilin via a trans-selective Suzuki coupling and subsequent Negishi-type methylation, and its biomimetic conversion to (+/-)-SNF4435C and (+/-)-SNF4435D is described. |
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