Pd(OH)2/C-mediated selective oxidation of silyl enol ethers by tert-butylhydroperoxide, a useful method for the conversion of ketones to alpha,beta-enones or beta-silyloxy-alpha,beta-enones |
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| Authors: | Yu Jin-Quan Wu Hai-Chen Corey E J |
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| Institution: | Department of Chemistry, Brandeis University, Waltham, Massachusetts 02454-9110, USA. |
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| Abstract: | reaction: see text] Pd(OH)2-catalyzed oxidation of silyl enol ethers by t-BuOOH gives either beta-silyloxy-alpha,beta-enones or alpha,beta-enones in good yields depending on the base used. |
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